Consider the reaction :
Cl₂(aq) + H₂S(aq) → S(s) + 2H⁺ (aq) + 2Cl^– (aq)
The rate equation for this reaction is rate = k [Cl₂] [H₂S]
Which of these mechanisms is/are consistent with this rate equation?
(A) Cl₂ + H₂S H⁺ + Cl^– + Cl⁺ + HS^– (slow)
Cl⁺ + HS^– H⁺ + Cl^– + S (fast)
(B) H₂S H⁺ + HS^– (fast equilibrium)
Cl₂ + HS^– 2Cl^– + H⁺ + S (slow)